Coulometry on the voltammetric timescale: Microdisk potential-step chronoamperometry in aprotic solvents reliably measures the number of electrons transferred in an electrode process simultaneously with the diffusion coefficients of the electroactive species

Microdisk, single potential-step chronoamperometry, is applied to a range of organic substrates in the aprotic solvents tetrahydrofuran, propylene carbonate, acetonitrile and the room temperature ionic liquid [C 4dmim][N(Tf)2]. Fitting of the chronoamperometric transients was achieved using the Shou...

Full description

Bibliographic Details
Main Authors: Paddon, C, Silvester, D, Bhatti, F, Donohoe, T, Compton, R
Format: Journal article
Language:English
Published: 2007