Coulometry on the voltammetric timescale: Microdisk potential-step chronoamperometry in aprotic solvents reliably measures the number of electrons transferred in an electrode process simultaneously with the diffusion coefficients of the electroactive species
Microdisk, single potential-step chronoamperometry, is applied to a range of organic substrates in the aprotic solvents tetrahydrofuran, propylene carbonate, acetonitrile and the room temperature ionic liquid [C 4dmim][N(Tf)2]. Fitting of the chronoamperometric transients was achieved using the Shou...
Main Authors: | Paddon, C, Silvester, D, Bhatti, F, Donohoe, T, Compton, R |
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Format: | Journal article |
Language: | English |
Published: |
2007
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