Photochemical unmasking of polyyne rotaxanes

Bulky photolabile masked alkyne equivalents (MAEs) are needed for the synthesis of polyyne polyrotaxanes, as insulated molecular wires and as stabilized forms of the linear polymeric allotrope of carbon, carbyne. We have synthesized a novel MAE based on phenanthrene and compared it with an indane-ba...

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Bibliographic Details
Main Authors: Woltering, S, Gawel, P, Christensen, KE, Thompson, AL, Anderson, HL
Format: Journal article
Language:English
Published: American Chemical Society 2020
Subjects: