Photochemical unmasking of polyyne rotaxanes
Bulky photolabile masked alkyne equivalents (MAEs) are needed for the synthesis of polyyne polyrotaxanes, as insulated molecular wires and as stabilized forms of the linear polymeric allotrope of carbon, carbyne. We have synthesized a novel MAE based on phenanthrene and compared it with an indane-ba...
Main Authors: | , , , , |
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Format: | Journal article |
Language: | English |
Published: |
American Chemical Society
2020
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Subjects: |