High-resolution (19)F MAS NMR spectroscopy: structural disorder and unusual J couplings in a fluorinated hydroxy-silicate.
High-resolution (19)F magic angle spinning (MAS) NMR spectroscopy is used to study disorder and bonding in a crystalline solid. (19)F MAS NMR reveals four distinct F sites in a 50% fluorine-substituted deuterated hydrous magnesium silicate (clinohumite, 4Mg(2)SiO(4)·Mg(OD(1-x)F(x))(2) with x = 0.5),...
Prif Awduron: | Griffin, J, Yates, JR, Berry, A, Wimperis, S, Ashbrook, SE |
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Fformat: | Journal article |
Iaith: | English |
Cyhoeddwyd: |
2010
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Eitemau Tebyg
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