Structure and bonding in the isoelectronic series CnHnP5-n+: is phosphorus a carbon copy?

The relative stabilities of different isomers of the isoelectronic series C(n)H(n)P(5-n)(+) have been investigated using G3X theory. The results indicate that all species containing one or more phosphorus atom adopt a three-dimensional nido geometry, in marked contrast to the planar structure favour...

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Bibliographic Details
Main Authors: Pantazis, D, McGrady, J, Lynam, J, Russell, C, Green, M
Format: Journal article
Language:English
Published: 2004