Direct observation of the conical intersection in cis-trans photoisomerization of rhodopsin

High-time-resolution broadband pump-probe spectroscopy of rhodopsin reveals the loss of reactant and appearance of photoproduct features within ≈100fs, which are signatures of a wavepacket moving through a conical intersection. Experiments are supported by molecular dynamics simulations. © Optical S...

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Bibliographic Details
Main Authors: Polli, D, Manzoni, C, Brida, D, Cerullo, G, Altoe, P, Tomasello, G, Orlandi, G, Garavelli, M, Weingart, O, Kukura, P, Spillane, K, Mathies, R
Format: Journal article
Language:English
Published: Optical Society of America 2009