Synthesis and structure of alkaline earth silicon nitrides: BaSiN(2), SrSiN(2), and CaSiN(2).
The alkaline earth silicon nitrides AESiN(2) (AE = Ca, Sr, Ba) are reported, synthesized as clear, colorless, single crystals from molten sodium at 900-1100 degrees C or, in the cases of BaSiN(2) and SrSiN(2), as white powders by reacting powdered intermetallics AESi with flowing anhydrous ammonia a...
| Main Authors: | , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2004
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