A theoretical and experimental approach to the adiabaticity of diffusional electron transfer processes. Electroreduction of 2-nitropropane on mercury microelectroelectrodes
A theoretical and experimental approach to the degree of adiabaticity of electrode processes is considered for the case where the electroactive species of the redox couple move freely in solution. Within a transition state-like framework, the adiabatic effect on the activation energy of electron tra...
Main Authors: | , , , |
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Format: | Journal article |
Language: | English |
Published: |
2013
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