Replacing dichloroethane as a solvent for rhodium-catalysed intermolecular alkyne hydroacylation reactions: the utility of propylene carbonate

Replacing dichloroethane as a solvent for rhodium-catalysed intermolecular alkyne hydroacylation reactions: the utility of propylene carbonate

Propylene carbonate is an excellent solvent for rhodium-catalysed intermolecular alkyne hydroacylation reactions, allowing a variety of β-S-aldehydes and alkynes to be combined in high yields, to deliver enone products. The effective use of propylene carbonate removes the need to employ dichloroetha...

書誌詳細
主要な著者:	Lenden, P, Ylioja, P, Gonzalez-Rodriguez, C, Entwistle, D, Willis, M
フォーマット:	Journal article
言語:	English
出版事項:	2011

類似資料

Tandem catalytic processes involving Rhodium-catalysed intermolecular hydroacylation
著者:: Lenden, P
出版事項: (2011)

Rhodium catalysed hydroacylation reactions in the synthesis of heterocycles
著者:: Ylioja, P
出版事項: (2011)

Rhodium-catalysed linear-selective alkyne hydroacylation.
著者:: Poingdestre, S, 等
出版事項: (2012)

Controlling selectivity in the rhodium-catalysed intermolecular hydroacylation reaction
著者:: Pawley, R
出版事項: (2012)

Mechanistic studies of rhodium-catalysed intermolecular hydroacylation
著者:: Barwick-Silk, J
出版事項: (2018)

Rhodium-catalysed intermolecular alkyne hydroacylation: the enantioselective synthesis of α- and β-substituted ketones by kinetic resolution.
著者:: González-Rodríguez, C, 等
出版事項: (2010)

An alkyne hydroacylation route to highly substituted furans.
著者:: Lenden, P, 等
出版事項: (2011)

Rhodium(I) catalysis for intermolecular alkyne hydroacylation and desymmetrisation
著者:: Moseley, D
出版事項: (2022)

Traceless chelation-controlled rhodium-catalyzed intermolecular alkene and alkyne hydroacylation.
著者:: Hooper, J, 等
出版事項: (2013)

Rhodium-catalyzed enantioselective intermolecular hydroacylation reactions
著者:: Gonzalez-Rodriguez, C, 等
出版事項: (2011)

Exploiting carbonyl groups to control intermolecular rhodium-catalyzed alkene and alkyne hydroacylation
著者:: Coxon, TJ, 等
出版事項: (2017)

Rhodium (I) catalyzed intermolecular hydroacylation.
著者:: Sapmaz, S, 等
出版事項: (2001)

α‐Amidoaldehydes as substrates in rhodium‐catalyzed intermolecular alkyne hydroacylation: The synthesis of α‐Amidoketones
著者:: Pal, R, 等
出版事項: (2020)

a-Amidoaldehydes as substrates in rhodium-catalyzed intermolecular alkyne hydroacylation: The synthesis of a-amidoketones
著者:: Pal, R, 等
出版事項: (2020)

Azine N-oxides as effective controlling groups for Rh-catalysed intermolecular alkyne hydroacylation
著者:: Moseley, DF, 等
出版事項: (2021)

O-substituted alkyl aldehydes for rhodium-catalyzed intermolecular alkyne hydroacylation: the utility of methylthiomethyl ethers.
著者:: Parsons, SR, 等
出版事項: (2011)

Exploring small bite-angle PNP and PCP ligands for the rhodium-catalysed intermolecular hydroacylation of b-s-substituted aldehydes with alkenes and alkynes
著者:: Pernik, I
出版事項: (2014)

Exploring and exploiting selectivity in Rhodium-catalysed hydroacylation reactions
著者:: Poingdestre, SJ
出版事項: (2012)

New applications of rhodium-catalysed hydroacylation
著者:: Iwumene, NUN
出版事項: (2022)

An enamine controlling group for rhodium-catalyzed intermolecular hydroacylation
著者:: Straker, R, 等
出版事項: (2018)

Rhodium-catalyzed intermolecular chelation controlled alkene and alkyne hydroacylation: synthetic scope of beta-S-substituted aldehyde substrates.
著者:: Willis, M, 等
出版事項: (2006)

Studies toward the application and development of rhodium-catalysed hydroacylation reactions
著者:: Neuhaus, J
出版事項: (2016)

Diversely substituted quinolines via rhodium-catalyzed alkyne hydroacylation
著者:: Willis, M, 等
出版事項: (2016)

Rhodium-catalysed hydroacylation or reductive aldol reactions: a ligand dependent switch of reactivity.
著者:: Osborne, J, 等
出版事項: (2008)

Applications of rhodium-catalysed hydroacylation in heterocycle synthesis
著者:: Majhail, M
出版事項: (2016)

New reactivity and selectivity in rhodium-catalysed hydroacylation
著者:: Pal, R
出版事項: (2020)

Exploiting rhodium-catalysed ynamide hydroacylation as a platform for divergent heterocycle synthesis
著者:: Straker, R, 等
出版事項: (2017)

Chelation-controlled intermolecular alkene and alkyne hydroacylation: the utility of beta-thioacetal aldehydes.
著者:: Willis, M, 等
出版事項: (2005)

Investigating rhodium-catalysed hydroacylation and carbon-carbon bond activation
著者:: Coxon, T
出版事項: (2017)

2-Aminobenzaldehydes as versatile substrates for rhodium-catalyzed alkyne hydroacylation: application to dihydroquinolone synthesis.
著者:: Castaing, M, 等
出版事項: (2013)

Rhodium-catalyzed branched-selective alkyne hydroacylation: a ligand-controlled regioselectivity switch.
著者:: González-Rodríguez, C, 等
出版事項: (2011)

Hydroacylation of Alkenes, Alkynes, and Allenes
著者:: Willis, M
出版事項: (2014)

Intermolecular rhodium catalyzed hydroacylation of allenes: the regioselective synthesis of beta,gamma-unsaturated ketones
著者:: Randell-Sly, H, 等
出版事項: (2009)

Intermolecular hydroacylation: high activity rhodium catalysts containing small-bite-angle diphosphine ligands.
著者:: Chaplin, AB, 等
出版事項: (2012)

Intermolecular Alkyne Hydroacylation. Mechanistic Insight from the Isolation of the Vinyl Intermediate That Precedes Reductive Elimination
著者:: Pawley, R, 等
出版事項: (2012)

Catalytic enantioselective intermolecular hydroacylation: rhodium-catalyzed combination of beta-S-aldehydes and 1,3-disubstituted allenes.
著者:: Osborne, J, 等
出版事項: (2008)

Transition metal catalyzed alkene and alkyne hydroacylation.
著者:: Willis, M
出版事項: (2010)

Synthesis of α,β-unsaturated ketones through nickel-catalysed aldehyde-free hydroacylation of alkynes
著者:: Joon Ho Rhlee, 等
出版事項: (2022-02-01)

Exploring Small Bite-Angle Ligands for the Rhodium-Catalyzed Intermolecular Hydroacylation of beta-S-Substituted Aldehydes with 1-Octene and 1-Octyne
著者:: Pernik, I, 等
出版事項: (2012)

Sequential catalysis: Exploiting a single rhodium(I) catalyst to promote an alkyne hydroacylation–aryl boronic acid conjugate addition sequence
著者:: Fernández, M, 等
出版事項: (2016)