Access to enhanced differences in Marcus–Hush and Butler–Volmer electron transfer theories by systematic analysis of higher order AC harmonics
The potential-dependences of the rate constants associated with heterogeneous electron transfer predicted by the empirically based Butler-Volmer and fundamentally based Marcus-Hush formalisms are well documented for dc cyclic voltammetry. However, differences are often subtle, so, presumably on the...
Main Authors: | Gillow, K, Stevenson, G, Baker, R, Kennedy, G, Bond, A, Gavaghan, D |
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Other Authors: | Spencelayh, M |
Format: | Journal article |
Language: | English |
Published: |
Royal Society of Chemistry
2012
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