A gallium hydride as an oxidizing agent: direct synthesis of IrV complexes via Ga-H bond activation
Reactions of the β-diketiminate-stabilized gallium dihydride (Nacnac)Dipp GaH2 with chelating IrI bis(phosphine) precursors under an H2 atmosphere are shown to provide a simple route to IrV complexes stabilized by strongly σ-donating hydrides and the carbene-like (Nacnac)Dipp Ga donor. Characterizat...
| Main Authors: | , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
Wiley
2017
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