A gallium hydride as an oxidizing agent: direct synthesis of IrV complexes via Ga-H bond activation
Reactions of the β-diketiminate-stabilized gallium dihydride (Nacnac)Dipp GaH2 with chelating IrI bis(phosphine) precursors under an H2 atmosphere are shown to provide a simple route to IrV complexes stabilized by strongly σ-donating hydrides and the carbene-like (Nacnac)Dipp Ga donor. Characterizat...
| मुख्य लेखकों: | , , , , |
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| स्वरूप: | Journal article |
| भाषा: | English |
| प्रकाशित: |
Wiley
2017
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| _version_ | 1826296987750760448 |
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| author | Caise, A Abdalla, J Tirfoin, R Edwards, A Aldridge, S |
| author_facet | Caise, A Abdalla, J Tirfoin, R Edwards, A Aldridge, S |
| author_sort | Caise, A |
| collection | OXFORD |
| description | Reactions of the β-diketiminate-stabilized gallium dihydride (Nacnac)Dipp GaH2 with chelating IrI bis(phosphine) precursors under an H2 atmosphere are shown to provide a simple route to IrV complexes stabilized by strongly σ-donating hydrides and the carbene-like (Nacnac)Dipp Ga donor. Characterization of these systems as seven-coordinate IrV tetrahydride species is supported by single crystal X-ray and neutron diffraction, and by T1 NMR measurements. By contrast related systems featuring more sterically demanding (non-chelating) ancillary ligands are better described in terms of a bis(hydride) dihydrogen [L3 Ir(H)2 (H2 )]+ formulation and a formal IrIII oxidation state. |
| first_indexed | 2024-03-07T04:24:45Z |
| format | Journal article |
| id | oxford-uuid:cc3dd538-ea14-4954-9f04-a1e0a4a1eb89 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T04:24:45Z |
| publishDate | 2017 |
| publisher | Wiley |
| record_format | dspace |
| spelling | oxford-uuid:cc3dd538-ea14-4954-9f04-a1e0a4a1eb892022-03-27T07:20:27ZA gallium hydride as an oxidizing agent: direct synthesis of IrV complexes via Ga-H bond activationJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:cc3dd538-ea14-4954-9f04-a1e0a4a1eb89EnglishSymplectic Elements at OxfordWiley2017Caise, AAbdalla, JTirfoin, REdwards, AAldridge, SReactions of the β-diketiminate-stabilized gallium dihydride (Nacnac)Dipp GaH2 with chelating IrI bis(phosphine) precursors under an H2 atmosphere are shown to provide a simple route to IrV complexes stabilized by strongly σ-donating hydrides and the carbene-like (Nacnac)Dipp Ga donor. Characterization of these systems as seven-coordinate IrV tetrahydride species is supported by single crystal X-ray and neutron diffraction, and by T1 NMR measurements. By contrast related systems featuring more sterically demanding (non-chelating) ancillary ligands are better described in terms of a bis(hydride) dihydrogen [L3 Ir(H)2 (H2 )]+ formulation and a formal IrIII oxidation state. |
| spellingShingle | Caise, A Abdalla, J Tirfoin, R Edwards, A Aldridge, S A gallium hydride as an oxidizing agent: direct synthesis of IrV complexes via Ga-H bond activation |
| title | A gallium hydride as an oxidizing agent: direct synthesis of IrV complexes via Ga-H bond activation |
| title_full | A gallium hydride as an oxidizing agent: direct synthesis of IrV complexes via Ga-H bond activation |
| title_fullStr | A gallium hydride as an oxidizing agent: direct synthesis of IrV complexes via Ga-H bond activation |
| title_full_unstemmed | A gallium hydride as an oxidizing agent: direct synthesis of IrV complexes via Ga-H bond activation |
| title_short | A gallium hydride as an oxidizing agent: direct synthesis of IrV complexes via Ga-H bond activation |
| title_sort | gallium hydride as an oxidizing agent direct synthesis of irv complexes via ga h bond activation |
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