Synthesis, structure, magnetism and cation ordering in Ba3-xSrxFe2O5Cu2Ch2 (x = 0, 1, 2; Ch = S, Se) and BaCa2Fe2O5Cu2S2

The layered oxide chalcogenides Ba3-xSrxFe2O5Cu2Ch2 (x ​= ​0, 1, 2; Ch ​= ​S, Se) and BaCa2Fe2O5Cu2S2 are reported here for the first time. They are isostructural with the previously reported Sr3Fe2O5Cu2Ch2, crystallising in the I4/mmm space group. This structure is related to the n ​= ​2 Ruddlesden...

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Bibliographic Details
Main Authors: Smyth, RD, Wilson, JAD, Manuel, P, Clarke, SJ
Format: Journal article
Language:English
Published: Elsevier 2021