Multimetallic Arrays: Symmetrical and Unsymmetrical Bi-, Tri-, and Tetrametallic Organometallic Complexes of Ruthenium(II) and Osmium(II)

The cationic complex [Ru(C(C=CPh)=CHPhXS2CNC4H 8NH2)(CO)(PPh3)2]+ was prepared from the reaction of [Ru(C(C=CPh)=CHPh)Cl(CO)(BTD)(PPh 3)2] (BID = 2,1,3-benzothiadiazole) with the zwitterionic dithiocarbamate H2NC4H8NCS2 and characterized structurally. In situ generation of the metalladithiocarbamate...

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Autors principals: Macgregor, M, Hogarth, G, Thompson, A, Wilton-Ely, J
Format: Journal article
Idioma:English
Publicat: 2009