Structure and dynamics of a dihydrogen/hydride ansa molybdenocene complex

Structure and dynamics of a dihydrogen/hydride ansa molybdenocene complex

Show other versions (1)

In contrast to [Cp2MoH3](+), which is a thermally stable trihydride complex, the ansa-bridged analogue [(eta-C5H4)(2)-CMe2MoH(H-2)](+) (1) is a thermally labile dihydrogen/hydride complex. Partial deuteration of the hydride ligands allows observation of J(H-D) = 11.9 Hz in 1-d(1) and 9.9 Hz in 1-d(2...

Deskribapen osoa

Xehetasun bibliografikoak
Egile Nagusiak:	Pons, V, Conway, S, Green, M, Green, J, Herbert, B, Heinekey, D
Formatua:	Journal article
Hizkuntza:	English
Argitaratua:	American Chemical Society 2004
Gaiak:	Chemistry & allied sciences Inorganic chemistry Organometallic Chemistry

Antzeko izenburuak

Hydrogen/deuterium exchange in alkyl-hydride derivatives of ansa-tungstenocene compounds
nork: Green, M, et al.
Argitaratua: (2005)

Structure–reactivity correlations in new W(IV) and Nb(IV) silicon-bridged ansa-metallocene hydrides
nork: Conway, S, et al.
Argitaratua: (2006)

Group 5 ansa-metallocenes: Structural and dynamic properties of tetrahydroborate complexes
nork: Conway, S, et al.
Argitaratua: (2000)

Studies of ansa-bis(cyclopentadienyl)tungsten derivatives
nork: Conway, S, et al.
Argitaratua: (1998)

Bridging-terminal exchange in ansa-bridged tetrahydroborate niobocene compounds: a density functional study
nork: Ashworth, N, et al.
Argitaratua: (2000)

Synthesis, structure and density functional study of the ansa-rhenocene complex [Re{(η-C5H4)CMe2(η-C5H4)}Cl]
nork: Conway, S, et al.
Argitaratua: (2000)

Structure and dynamics of a dihydrogen/hydride ansa molybdenocene complex.
nork: Pons, V, et al.
Argitaratua: (2004)

Structure reactivity relationships in metallocene chemistry: the ansa-effect
nork: Conway, S
Argitaratua: (2000)

Solution reactivity studies of group 15 Zintl anions towards unsaturated substrates
nork: Turbervill, R
Argitaratua: (2014)

The synthesis and reactivity of cationic terminal borylene complexes
nork: Pierce, G, et al.
Argitaratua: (2010)

Indenyl and diazene chemistry
nork: Ransom, P
Argitaratua: (2009)

Alkaline earth complexes supported by chelating diamido ligands
nork: Haynes, M
Argitaratua: (2024)

POP-type rhodium complexes in amine borane dehydropolymerisation
nork: Adams, G
Argitaratua: (2018)

Borane, boryl and borylene complexes of electron rich metal centres
nork: Addy, D, et al.
Argitaratua: (2012)

Exploring the reactivity of cationic rhodium xantphos complexes with amine-boranes
nork: Johnson, H
Argitaratua: (2015)

Alkaline earth hydroborate complexes for the ring-opening polymerisation of cyclic esters
nork: Diteepeng, N
Argitaratua: (2018)

Chemical reactivity of group 14 [E9]4– and 15 [E'7]3– Zintl ions
nork: Espinoza Quintero, G
Argitaratua: (2015)

Direct assignment of EPR spectra to structurally defined iron-sulfur clusters in complex I by double electron-electron resonance
nork: Roessler, M, et al.
Argitaratua: (2010)

Synthesis and reactivity of alkaline earth and aluminium gallyl complexes
nork: Reyes Sánchez, JA
Argitaratua: (2018)

Group four permethylindenyl-phenoxy (PHENI*) complexes for the synthesis of polyolefins
nork: Collins Rice, CG
Argitaratua: (2023)

Alkaline earth and rare earth complexes for the ring opening polymerisation of cyclic esters
nork: Clark, L
Argitaratua: (2012)

Controlling selectivity in the rhodium-catalysed intermolecular hydroacylation reaction
nork: Pawley, R
Argitaratua: (2012)

Cationic rhodium complexes with chelating phosphine and phosphine alkene ligands. Application in dehydrogenation and dehydrocoupling reactions
nork: Dallanegra, R
Argitaratua: (2011)

Dioxygen Activation by Internally Aromatic Metallacycle: Crystallographic Structure and Mechanistic Investigations
nork: Zhihong Deng, et al.
Argitaratua: (2020-08-01)

High-resolution x-ray spectroscopic study of the electronic structure of the prototypical p-type transparent conducting oxide CuAlO2
nork: Aston, D, et al.
Argitaratua: (2005)

Photoemission and STM study of the electronic structure of Nb-doped TiO2
nork: Morris, D, et al.
Argitaratua: (2000)

Olefin polymerisation using group 4 permethylindenyl complexes
nork: Thomas Williams
Argitaratua: (2020)

New scandium and titanium borylimido chemistry
nork: Clough, B
Argitaratua: (2017)

Mechanistic studies of rhodium-catalysed intermolecular hydroacylation
nork: Barwick-Silk, J
Argitaratua: (2018)

Synthesis and characterization of WS₂ inorganic nanotubes with encapsulated/intercalated CsI
nork: Hong, S, et al.
Argitaratua: (2010)

Exploring the reactivity patterns of cationic and neutral rhodium bis-phosphine species with amine-boranes
nork: Sewell, LJ
Argitaratua: (2013)

Solution reactivity studies of group 14 zintyl clusters towards organometallic reagents
nork: Zhou, B
Argitaratua: (2012)

Frustrated Lewis pairs derived from xanthene and related backbones
nork: Zulkifly, IAB
Argitaratua: (2020)

Inorganic and organometallic : a bibliography SKOTO 111 /
Argitaratua: (1994)

Nature of band-gap states in V-doped TiO2 revealed by resonant photoemission
nork: Morris, D, et al.
Argitaratua: (1997)

n-type doping in Cd2SnO4: a study by EELS and photoemission
nork: Dou, Y, et al.
Argitaratua: (1996)

Anion-templated synthesis of functional interlocked architectures
nork: Hancock, L
Argitaratua: (2011)

Solvothermal synthesis of N-doped TiO₂ nanotubes for visible-light-responsive photocatalysis
nork: Jiang, Z, et al.
Argitaratua: (2008)

A study of core and valence levels in β-PbO₂ by hard X-ray photoemission
nork: Payne, D, et al.
Argitaratua: (2009)

Band-gap shrinkage in n-type-doped CdO probed by photoemission spectroscopy
nork: Dou, Y, et al.
Argitaratua: (1997)