Structure and dynamics of a dihydrogen/hydride ansa molybdenocene complex

Structure and dynamics of a dihydrogen/hydride ansa molybdenocene complex

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In contrast to [Cp2MoH3](+), which is a thermally stable trihydride complex, the ansa-bridged analogue [(eta-C5H4)(2)-CMe2MoH(H-2)](+) (1) is a thermally labile dihydrogen/hydride complex. Partial deuteration of the hydride ligands allows observation of J(H-D) = 11.9 Hz in 1-d(1) and 9.9 Hz in 1-d(2...

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Bibliografische gegevens
Hoofdauteurs:	Pons, V, Conway, S, Green, M, Green, J, Herbert, B, Heinekey, D
Formaat:	Journal article
Taal:	English
Gepubliceerd in:	American Chemical Society 2004
Onderwerpen:	Chemistry & allied sciences Inorganic chemistry Organometallic Chemistry

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