Structure and dynamics of a dihydrogen/hydride ansa molybdenocene complex
In contrast to [Cp2MoH3](+), which is a thermally stable trihydride complex, the ansa-bridged analogue [(eta-C5H4)(2)-CMe2MoH(H-2)](+) (1) is a thermally labile dihydrogen/hydride complex. Partial deuteration of the hydride ligands allows observation of J(H-D) = 11.9 Hz in 1-d(1) and 9.9 Hz in 1-d(2...
| Main Authors: | , , , , , |
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| Formato: | Journal article |
| Idioma: | English |
| Publicado: |
American Chemical Society
2004
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| Subjects: |