Coordination diversity in hydrogen-bonded homoleptic fluoride–alcohol complexes modulates reactivity
The nucleophilic reactivity of fluoride ion is altered in the presence of hydrogen-bond donors, including alcohols. Relatively little is known about the coordination involved; to rectify this, the X-ray structures of fourteen novel fluoride-alcohol complexes with tetrabutylammonium as the counterion...
| Main Authors: | , , , , , , , |
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| Format: | Journal article |
| Published: |
Royal Society of Chemistry
2016
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