New binuclear alkyl and half-sandwich cyclopentadienyl imido titanium complexes containing acetamidinate and benzamidinate supporting ligands

Chloride metathesis reactions of the binuclear titanium N,N′-bis(cyclohexyl)acetamidinato-μ-imido compound [Ti2(μ-NBut)2{MeC(NC6H11)2}2Cl2] (1) and the mononuclear N,N′-bis(trimethylsilyl)benzamidinato-imido analogue [Ti(NBut){PhC(NSiMe3)2}Cl(py)2] (2) are described. Thus, reaction of 1 or 2 with Li...

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Bibliographic Details
Main Authors: Stewart, P, Blake, A, Mountford, P
Format: Journal article
Language:English
Published: 1998