Polyethyl substituted weakly coordinating carborane anions: a sequential dehydrogenative borylation-hydrogenation route.

Polyethyl substituted weakly coordinating carborane anions: a sequential dehydrogenative borylation-hydrogenation route.

Polyethylated carborane monoanions based on [closo-CB11H12]- with up to five B-ethyl groups can be prepared by a sequential Rh-catalysed dehydrogenative borylation then hydrogenation.

Bibliografische gegevens
Hoofdauteurs:	Molinos, E, Kociok-Köhn, G, Weller, A
Formaat:	Journal article
Taal:	English
Gepubliceerd in:	2005

Gelijkaardige items

Sequential dehydrogenative borylation/hydrogenation route to polyethyl-substituted, weakly coordinating carborane anions
door: Molinos, E, et al.
Gepubliceerd in: (2007)

Cationic rhodium mono-phosphine fragments partnered with carborane monoanions [closo-CB11H6X6]- (X = H, Br). Synthesis, structures and reactivity with alkenes.
door: Molinos, E, et al.
Gepubliceerd in: (2007)

The role of halogenated carborane monoanions in olefin hydrogenation catalysed by cationic iridium phosphine complexes.
door: Moxham, G, et al.
Gepubliceerd in: (2006)

Rhodium-catalyzed dehydrogenative borylation of cyclic alkenes
door: Kondoh, Azusa, et al.
Gepubliceerd in: (2013)

[1-Me-1-closo-SnB11 H-11](-) as a potential weakly coordinating anion: Synthesis of Rh(PPh3)(2)(1-Me-closo-SnB11 H-11) and comparisons with Rh(PR3)(2) (1-H-closo-CB11 H-(11))
door: Molinos, E, et al.
Gepubliceerd in: (2006)

B-C activation in highly alkylated carborane monoanions partnered with cationic transition metal fragments: observations and comments
door: Ingleson, M, et al.
Gepubliceerd in: (2005)

Ferrocenyl substituted carboranes: synthesis and characterisation
door: Beckering, C, et al.
Gepubliceerd in: (1998)

Iridium-catalysed regioselective borylation of carboranes via direct B–H activation
door: Ruofei Cheng, et al.
Gepubliceerd in: (2017-03-01)

Approaching a “naked” boryl anion: amide metathesis as a route to calcium, strontium, and potassium boryl complexes
door: Protchenko, AV, et al.
Gepubliceerd in: (2020)

The coordination chemistry of boryl and borate substituted cyclopentadienyl ligands
door: Aldridge, S, et al.
Gepubliceerd in: (2003)

Transition metal complexes of the weakly coordinating carborane anion [CB11H12](-): the first isolation and structural characterisation of an intermediate in a silver salt metathesis reaction
door: Patmore, N, et al.
Gepubliceerd in: (2000)

Rhodium phosphine olefin complexes of the weakly coordinating anions [BAr4F](-) and [1-closo-CB11H6Br6](-). Kinetic versus thermodynamic factors in anion coordination and complex reactivity
door: Douglas, T, et al.
Gepubliceerd in: (2007)

Studies in Selective C-C Bond Formation via Borylation and Dehydrogenation
door: Barbour, Johanna Christine
Gepubliceerd in: (2022)

Antibacterial Effect of Zirconia Nanoparticles on Polyethyl Methacrylate Resin for Provisional Crowns
door: Kim HS, et al.
Gepubliceerd in: (2022-12-01)

Silver-phosphine complexes of the highly methylated carborane monoanion [closo-1-H-CB11Me11]-.
door: Clarke, A, et al.
Gepubliceerd in: (2004)

Carboranes, including their metal complexes
door: Weller, A
Gepubliceerd in: (2001)

Intramolecular alkyl phosphine dehydrogenation in cationic rhodium complexes of tris(cyclopentylphosphine).
door: Douglas, T, et al.
Gepubliceerd in: (2008)

Substitution chemistry of sterically demanding boryl ligands
door: Coombs, D, et al.
Gepubliceerd in: (2003)

Ligand design: the two faces of carboranes.
door: Weller, A
Gepubliceerd in: (2011)

Carboranes /
door: 242138 Grimes, Russell N.
Gepubliceerd in: (1970)

Dialkylboryl-Substituted Cyclic Disilenes Synthesized by Desilylation-Borylation of Trimethylsilyl-Substituted Disilenes
door: Kaho Tanaka, et al.
Gepubliceerd in: (2021-03-01)

Transition metal boryl and borylene complexes: substitution and abstraction chemistry
door: Aldridge, S, et al.
Gepubliceerd in: (2004)

Quadruple C-H activation coupled to hydrofunctionalization and C-H silylation/borylation enabled by weakly coordinated palladium catalyst
door: Bo-Cheng Tang, et al.
Gepubliceerd in: (2020-11-01)

Variable coordination modes and catalytic dehydrogenation of B-phenyl amine-boranes.
door: Kumar, A, et al.
Gepubliceerd in: (2016)

Boryl substituted group 13 metallylenes: complexes with an iron carbonyl fragment.
door: Dange, D, et al.
Gepubliceerd in: (2016)

Tri(boryl)alkanes and Tri(boryl)alkenes: The Versatile Reagents
door: Oriol Salvadó, et al.
Gepubliceerd in: (2020-04-01)

Enhancement of Aggregation-Induced Emission by Introducing Multiple o-Carborane Substitutions into Triphenylamine
door: Kenta Nishino, et al.
Gepubliceerd in: (2017-11-01)

Phosphine-olefin ligands: a facile dehydrogenative route to catalytically active rhodium complexes.
door: Douglas, T, et al.
Gepubliceerd in: (2006)

Rhodium cyclooctadiene complexes of the weakly co-ordinating carborane anion [closo-CB11H12](-). Isolation and crystal structures of [(COD)Rh(eta(2)-CB11H12)] and [(COD)Rh(THF)(2)][CB11H12]
door: Weller, A, et al.
Gepubliceerd in: (2000)

Silver and Copper Complexes with closo-Polyhedral Borane, Carborane and Metallacarborane Anions: Synthesis and X-ray Structure
door: Varvara V. Avdeeva, et al.
Gepubliceerd in: (2016-05-01)

Re-design and evaluation of diclofenac-based carborane-substituted prodrugs and their anti-cancer potential
door: Christoph Selg, et al.
Gepubliceerd in: (2024-12-01)

Reevaluating ortho-Carborane Synthesis: Success with Mono-Substituted Acetylenes in the Presence of Silver Salts
door: Oleh V. Svaliavyn, et al.
Gepubliceerd in: (2024-12-01)

Boosting 2000‐Fold Hypergolic Ignition Rate of Carborane by Substitutes Migration in Metal Clusters
door: Jia‐Hong Huang, et al.
Gepubliceerd in: (2024-06-01)

Bi- and tri-metallic {Cp*RhCl} fragments partnered with carborane monoanions [CB11H6Y6](-) (Y = H, Br): control of nuclearity by choice of anion
door: Patmore, N, et al.
Gepubliceerd in: (2003)

Crystal Engineering of Cation-Radical Salts with Weakly Coordinating Carbadodecaborate Anions
door: Emmanuel Adeniyi, et al.
Gepubliceerd in: (2023-01-01)

[Cp2ZrMe(12-mu-Me-1-closo-CB11HMe10)]: a transition metal complex of a highly-methylated carborane anion.
door: Ingleson, M, et al.
Gepubliceerd in: (2003)

Transition metal boryl complexes
door: Kays, D, et al.
Gepubliceerd in: (2008)

Direct borylation of terrylene and quaterrylene
door: Haruka Kano, et al.
Gepubliceerd in: (2020-04-01)

Hydrophilic Ionic Liquid Mixtures of Weakly and Strongly Coordinating Anions with and without Water
door: Roberto Macchieraldo, et al.
Gepubliceerd in: (2018-08-01)

Activation of protic, hydridic and apolar E−H bonds by a boryl‐substituted GeII cation
door: Mangan, R, et al.
Gepubliceerd in: (2019)