Naked deltahedral silicon clusters in solution: synthesis and characterization of Si9(3-) and Si5(2-).

Elusive for over 100 years, deltahedral Zintl ions of silicon are finally synthesized and structurally characterized. The two clusters reported here, Si93- and Si52-, are analogous to known clusters of the heavier members of this group: Ge, Sn, and Pb.

Bibliographic Details
Main Authors: Goicoechea, J, Sevov, S
Format: Journal article
Language:English
Published: 2004