ORIENTATION OF COBALTOCENIUM CATIONS INTERCALATED INTO THE V2O5.1.6H(2)O XEROGEL DETERMINED BY SOLID-STATE H-2 NMR-SPECTROSCOPY
The orientations of [Co(C5D5)2] + ions intercalated in the xerogel V2O5· 1.6H2O have been studied using solid-state 2H NMR spectroscopy. The cobaltocenium ions in microcrystalline samples of V 2O5{Co(C5D5)2} 0.2(H2O)0.5 are observed to be held rigidly in the lattice at all temperatures up to 450 K....
| Main Authors: | , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
1995
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