Excitonic coupling dominates the homogeneous photoluminescence excitation linewidth in semicrystalline polymeric semiconductors

We measure and model the homogeneous excitation linewidth of regioregular poly(3-hexylthiophene), a model semicrystalline polymeric semiconductor, by means of two-dimensional coherent photoluminescence excitation spectroscopy. At a temperature of 8 K, we extract a linewidth of ∼ 90 meV full width...

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Bibliographic Details
Main Authors: Grégoire, P, Vella, E, Dyson, M, Bazán, C, Leonelli, R, Stingelin, N, Stavrinou, P, Bittner, E, Silva, C
Format: Journal article
Published: American Physical Society 2017