LOW-DIMENSIONAL ORGANOMETALLIC ELECTRON-TRANSFER COMPLEXES - X-RAY STRUCTURES AND MAGNETIC-PROPERTIES OF ALPHA-[CR(C6ME3H3)2].+[TCNQ].- AND BETA-[CR(C6ME3H3)2].+[TCNQ].-
The reaction of donor, Cr(arene)2 (arene = C6Me6 and C6Me3H3), D, with the acceptor TCNQ, A, results in formation of electron-transfer salts of [D].+[A].- composition. Two phases of [Cr(C6Me3H3)2] .+[TCNQ].- have been structurally characterized. The α-phase belongs to the centrosymmetric C2/c space...
| Main Authors: | , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
1990
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