Beta-agostic silylamido and silyl-hydrido compounds of molybdenum and tungsten.
Reactions of bis(imido) compounds (RN)(2)Mo(PMe(3))(n) (n = 2, R = (t)Bu; n = 3, R =2,6-dimethylphenyl (Ar') and 2,6-diisopropylphenyl (Ar)) and (RN)(2)W(PMe(3))(3) (R = 2,6-dimethylphenyl and 2,6-diisopropylphenyl) with silanes afford four types of products: the beta-agostic silylamido compoun...
| Main Authors: | , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2009
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