A concise total synthesis of (+/-)-1-epiaustraline.
[reaction: see text] A concise total synthesis of 1-epiaustraline 3 is described that utilizes a diastereoselective Birch reduction of an electron-deficient pyrrole and a chelation-controlled vinyl Grignard addition to an aldehyde to introduce the C7 stereocenter. The C1 and C2 stereocenters were se...
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Detalhes bibliográficos
| Principais autores: |
Donohoe, T,
Sintim, H |
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| Formato: | Journal article
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| Idioma: | English |
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| Publicado em: |
2004
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