A concise total synthesis of (+/-)-1-epiaustraline.

[reaction: see text] A concise total synthesis of 1-epiaustraline 3 is described that utilizes a diastereoselective Birch reduction of an electron-deficient pyrrole and a chelation-controlled vinyl Grignard addition to an aldehyde to introduce the C7 stereocenter. The C1 and C2 stereocenters were se...

Бүрэн тодорхойлолт

Номзүйн дэлгэрэнгүй
Үндсэн зохиолчид: Donohoe, T, Sintim, H
Формат: Journal article
Хэл сонгох:English
Хэвлэсэн: 2004