The role of halogenated carborane monoanions in olefin hydrogenation catalysed by cationic iridium phosphine complexes.
Iridium hydridophosphine complexes of general formula [Ir(PR3)2H2(anion)](PR3= PPh3, PMe2Ph; anion =[1-closo-CB(11)H(6)Cl(6)]-, [1-closo-CB(11)H(6)I(6)]-, [BAr(F)4]-) have been prepared by hydrogenation of cyclooctadiene precursor complexes. Solid-state structures of selected examples of these compl...
| Autors principals: | , , , , , |
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| Format: | Journal article |
| Idioma: | English |
| Publicat: |
2006
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