The role of halogenated carborane monoanions in olefin hydrogenation catalysed by cationic iridium phosphine complexes.

The role of halogenated carborane monoanions in olefin hydrogenation catalysed by cationic iridium phosphine complexes.

Iridium hydridophosphine complexes of general formula [Ir(PR3)2H2(anion)](PR3= PPh3, PMe2Ph; anion =[1-closo-CB(11)H(6)Cl(6)]-, [1-closo-CB(11)H(6)I(6)]-, [BAr(F)4]-) have been prepared by hydrogenation of cyclooctadiene precursor complexes. Solid-state structures of selected examples of these compl...

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Detalles Bibliográficos
Main Authors: Moxham, G, Douglas, T, Brayshaw, S, Kociok-Köhn, G, Lowe, J, Weller, A
Formato: Journal article
Idioma:English
Publicado: 2006

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