Synthesis and reactivity of nickel-stabilised µ2:η2,η2-P2, As2 and PAs units
The reactivity of two paramagnetic nickel(I) compounds, CpNi(NHC) (where Cp = cyclopentadienyl; NHC = 1,3-bis(2,4,6-trimethylphenyl)-imidazol-2-ylidene (IMes) or 1,3-bis(2,6-diisopropylphenyl)-imidazol-2-ylidene (IPr)), towards [Na(dioxane)x][PnCO] (Pn = P, As) is described. These reactions afford s...
| Main Authors: | , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
Wiley
2017
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