Chemical instability promotes apparent electrochemical irreversibility: Studies on the electrode kinetics of the one electron reduction of the 2,6-diphenylpyrylium cation in acetonitrile solution
Concentration profiles are obtained via numerical solution for the species involved in EC and EC2 mechanisms in a tubular flow cell. Voltammetric waves are simulated and the effect of the kinetic parameters on the waveshape is studied by considering the mass transport corrected Tafel slope. It is de...
| Main Authors: | , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2007
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