Chemical instability promotes apparent electrochemical irreversibility: Studies on the electrode kinetics of the one electron reduction of the 2,6-diphenylpyrylium cation in acetonitrile solution

Concentration profiles are obtained via numerical solution for the species involved in EC and EC2 mechanisms in a tubular flow cell. Voltammetric waves are simulated and the effect of the kinetic parameters on the waveshape is studied by considering the mass transport corrected Tafel slope. It is de...

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Những tác giả chính: Streeter, I, Jenkinson, S, Fleet, G, Compton, R
Định dạng: Journal article
Ngôn ngữ:English
Được phát hành: 2007