Highly (E)-selective Wadsworth-Emmons reactions promoted by methylmagnesium bromide.
An experimentally simple protocol for the very highly (E)-selective Wadsworth-Emmons reaction [(E):(Z) selectivities in excess of 180:1 in some cases] of a range of straight-chain and branched aliphatic, substituted aromatic, and base-sensitive aldehydes via reaction with an alkyl diethylphosphonoac...
Main Authors: | , , , , , , , |
---|---|
Format: | Journal article |
Language: | English |
Published: |
2008
|
_version_ | 1826299021243711488 |
---|---|
author | Claridge, T Davies, S Lee, J Nicholson, R Roberts, P Russell, A Smith, A Toms, S |
author_facet | Claridge, T Davies, S Lee, J Nicholson, R Roberts, P Russell, A Smith, A Toms, S |
author_sort | Claridge, T |
collection | OXFORD |
description | An experimentally simple protocol for the very highly (E)-selective Wadsworth-Emmons reaction [(E):(Z) selectivities in excess of 180:1 in some cases] of a range of straight-chain and branched aliphatic, substituted aromatic, and base-sensitive aldehydes via reaction with an alkyl diethylphosphonoacetate and MeMgBr is reported. |
first_indexed | 2024-03-07T04:55:34Z |
format | Journal article |
id | oxford-uuid:d67dfa1f-28be-497e-b32c-d974b27d22d4 |
institution | University of Oxford |
language | English |
last_indexed | 2024-03-07T04:55:34Z |
publishDate | 2008 |
record_format | dspace |
spelling | oxford-uuid:d67dfa1f-28be-497e-b32c-d974b27d22d42022-03-27T08:33:53ZHighly (E)-selective Wadsworth-Emmons reactions promoted by methylmagnesium bromide.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:d67dfa1f-28be-497e-b32c-d974b27d22d4EnglishSymplectic Elements at Oxford2008Claridge, TDavies, SLee, JNicholson, RRoberts, PRussell, ASmith, AToms, SAn experimentally simple protocol for the very highly (E)-selective Wadsworth-Emmons reaction [(E):(Z) selectivities in excess of 180:1 in some cases] of a range of straight-chain and branched aliphatic, substituted aromatic, and base-sensitive aldehydes via reaction with an alkyl diethylphosphonoacetate and MeMgBr is reported. |
spellingShingle | Claridge, T Davies, S Lee, J Nicholson, R Roberts, P Russell, A Smith, A Toms, S Highly (E)-selective Wadsworth-Emmons reactions promoted by methylmagnesium bromide. |
title | Highly (E)-selective Wadsworth-Emmons reactions promoted by methylmagnesium bromide. |
title_full | Highly (E)-selective Wadsworth-Emmons reactions promoted by methylmagnesium bromide. |
title_fullStr | Highly (E)-selective Wadsworth-Emmons reactions promoted by methylmagnesium bromide. |
title_full_unstemmed | Highly (E)-selective Wadsworth-Emmons reactions promoted by methylmagnesium bromide. |
title_short | Highly (E)-selective Wadsworth-Emmons reactions promoted by methylmagnesium bromide. |
title_sort | highly e selective wadsworth emmons reactions promoted by methylmagnesium bromide |
work_keys_str_mv | AT claridget highlyeselectivewadsworthemmonsreactionspromotedbymethylmagnesiumbromide AT daviess highlyeselectivewadsworthemmonsreactionspromotedbymethylmagnesiumbromide AT leej highlyeselectivewadsworthemmonsreactionspromotedbymethylmagnesiumbromide AT nicholsonr highlyeselectivewadsworthemmonsreactionspromotedbymethylmagnesiumbromide AT robertsp highlyeselectivewadsworthemmonsreactionspromotedbymethylmagnesiumbromide AT russella highlyeselectivewadsworthemmonsreactionspromotedbymethylmagnesiumbromide AT smitha highlyeselectivewadsworthemmonsreactionspromotedbymethylmagnesiumbromide AT tomss highlyeselectivewadsworthemmonsreactionspromotedbymethylmagnesiumbromide |