Rhodium(I) catalysis for intermolecular alkyne hydroacylation and desymmetrisation

Rhodium(I) catalysis for intermolecular alkyne hydroacylation and desymmetrisation

<p>This thesis discloses the uses and development of rhodium(I) catalysis within intermolecular hydroacylation and asymmetric [2+2+2] cycloadditions.</p> <p><b>Chapter 1</b> provides a general overview of the key methods and tethering strategies within the field rhodiu...

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Bibliografische gegevens
Hoofdauteur:	Moseley, D
Andere auteurs:	Willis, M
Formaat:	Thesis
Taal:	English
Gepubliceerd in:	2022
Onderwerpen:	Chemistry, Organic Synthesis

Gelijkaardige items

Tandem catalytic processes involving Rhodium-catalysed intermolecular hydroacylation
door: Lenden, P
Gepubliceerd in: (2011)

Mechanistic studies of rhodium-catalysed intermolecular hydroacylation
door: Barwick-Silk, J
Gepubliceerd in: (2018)

Rhodium catalysed hydroacylation reactions in the synthesis of heterocycles
door: Ylioja, P
Gepubliceerd in: (2011)

Controlling selectivity in the rhodium-catalysed intermolecular hydroacylation reaction
door: Pawley, R
Gepubliceerd in: (2012)

Exploring and exploiting selectivity in Rhodium-catalysed hydroacylation reactions
door: Poingdestre, SJ
Gepubliceerd in: (2012)

Traceless chelation-controlled rhodium-catalyzed intermolecular alkene and alkyne hydroacylation.
door: Hooper, J, et al.
Gepubliceerd in: (2013)

New applications of rhodium-catalysed hydroacylation
door: Iwumene, NUN
Gepubliceerd in: (2022)

Rhodium (I) catalyzed intermolecular hydroacylation.
door: Sapmaz, S, et al.
Gepubliceerd in: (2001)

Exploiting carbonyl groups to control intermolecular rhodium-catalyzed alkene and alkyne hydroacylation
door: Coxon, TJ, et al.
Gepubliceerd in: (2017)

Exploring small bite-angle PNP and PCP ligands for the rhodium-catalysed intermolecular hydroacylation of b-s-substituted aldehydes with alkenes and alkynes
door: Pernik, I
Gepubliceerd in: (2014)

Applications of rhodium-catalysed hydroacylation in heterocycle synthesis
door: Majhail, M
Gepubliceerd in: (2016)

α‐Amidoaldehydes as substrates in rhodium‐catalyzed intermolecular alkyne hydroacylation: The synthesis of α‐Amidoketones
door: Pal, R, et al.
Gepubliceerd in: (2020)

a-Amidoaldehydes as substrates in rhodium-catalyzed intermolecular alkyne hydroacylation: The synthesis of a-amidoketones
door: Pal, R, et al.
Gepubliceerd in: (2020)

New reactivity and selectivity in rhodium-catalysed hydroacylation
door: Pal, R
Gepubliceerd in: (2020)

O-substituted alkyl aldehydes for rhodium-catalyzed intermolecular alkyne hydroacylation: the utility of methylthiomethyl ethers.
door: Parsons, SR, et al.
Gepubliceerd in: (2011)

Rhodium-catalysed linear-selective alkyne hydroacylation.
door: Poingdestre, S, et al.
Gepubliceerd in: (2012)

Rhodium-catalyzed enantioselective intermolecular hydroacylation reactions
door: Gonzalez-Rodriguez, C, et al.
Gepubliceerd in: (2011)

Replacing dichloroethane as a solvent for rhodium-catalysed intermolecular alkyne hydroacylation reactions: the utility of propylene carbonate
door: Lenden, P, et al.
Gepubliceerd in: (2011)

Rhodium-catalysed intermolecular alkyne hydroacylation: the enantioselective synthesis of α- and β-substituted ketones by kinetic resolution.
door: González-Rodríguez, C, et al.
Gepubliceerd in: (2010)

An enamine controlling group for rhodium-catalyzed intermolecular hydroacylation
door: Straker, R, et al.
Gepubliceerd in: (2018)

Rhodium-catalyzed intermolecular chelation controlled alkene and alkyne hydroacylation: synthetic scope of beta-S-substituted aldehyde substrates.
door: Willis, M, et al.
Gepubliceerd in: (2006)

Azine N-oxides as effective controlling groups for Rh-catalysed intermolecular alkyne hydroacylation
door: Moseley, DF, et al.
Gepubliceerd in: (2021)

Diversely substituted quinolines via rhodium-catalyzed alkyne hydroacylation
door: Willis, M, et al.
Gepubliceerd in: (2016)

Ketone synthesis via rhodium-catalyzed traceless chelation-controlled hydroacylation reactions
door: Gao, M
Gepubliceerd in: (2018)

Cobalt-catalyzed intermolecular hydroacylation of olefins through chelation-assisted imidoyl C-H activation
door: Yang, Junfeng, et al.
Gepubliceerd in: (2015)

Sequential catalysis: Exploiting a single rhodium(I) catalyst to promote an alkyne hydroacylation–aryl boronic acid conjugate addition sequence
door: Fernández, M, et al.
Gepubliceerd in: (2016)

Chelation-controlled intermolecular alkene and alkyne hydroacylation: the utility of beta-thioacetal aldehydes.
door: Willis, M, et al.
Gepubliceerd in: (2005)

Enantioselective desymmetrisation towards the synthesis of daphniphyllum alkaloids
door: Ellis, SR
Gepubliceerd in: (2019)

2-Aminobenzaldehydes as versatile substrates for rhodium-catalyzed alkyne hydroacylation: application to dihydroquinolone synthesis.
door: Castaing, M, et al.
Gepubliceerd in: (2013)

Rhodium-catalyzed branched-selective alkyne hydroacylation: a ligand-controlled regioselectivity switch.
door: González-Rodríguez, C, et al.
Gepubliceerd in: (2011)

Intermolecular rhodium catalyzed hydroacylation of allenes: the regioselective synthesis of beta,gamma-unsaturated ketones
door: Randell-Sly, H, et al.
Gepubliceerd in: (2009)

Intermolecular hydroacylation: high activity rhodium catalysts containing small-bite-angle diphosphine ligands.
door: Chaplin, AB, et al.
Gepubliceerd in: (2012)

Intermolecular Alkyne Hydroacylation. Mechanistic Insight from the Isolation of the Vinyl Intermediate That Precedes Reductive Elimination
door: Pawley, R, et al.
Gepubliceerd in: (2012)

Hydroacylation of Alkenes, Alkynes, and Allenes
door: Willis, M
Gepubliceerd in: (2014)

Abnormal N-heterocyclic carbene gold(I) complexes : synthesis, structure, and catalysis in hydration of alkynes
door: Xu, Xiangya, et al.
Gepubliceerd in: (2013)

Cobalt-catalyzed arylzincation of alkynes and alkenes involving 1,4-cobalt migration
door: Tan, Boon Hong
Gepubliceerd in: (2015)

Catalytic enantioselective intermolecular hydroacylation: rhodium-catalyzed combination of beta-S-aldehydes and 1,3-disubstituted allenes.
door: Osborne, J, et al.
Gepubliceerd in: (2008)

Transition metal catalysis in the presence of fluorinating reagents
door: Hopkinson, M
Gepubliceerd in: (2011)

Oxidant free rhodium-catalyzed C-C bond formation via C-H bond activation
door: Feng, Daming
Gepubliceerd in: (2016)

The reaction of [Cp*RhCl2]2, aniline, and a terminal alkyne : formation of cyclometalated rhodium(III) complexes
door: Kumaran, Elumalai, et al.
Gepubliceerd in: (2014)