Bis-anthracene fused porphyrins: synthesis, crystal structure, and near-IR absorption.
Synthesis of fused bis-anthracene porphyrin monomers and dimers has been achieved by oxidative ring closure using FeCl(3) and Sc(OTf)(3)/DDQ, respectively. The fused compounds display red-shifted absorption spectra with maxima in the near-IR at 973 and 1495 nm, respectively, and small electrochemica...
Main Authors: | , , |
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Format: | Journal article |
Language: | English |
Published: |
2010
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