Bis-anthracene fused porphyrins: synthesis, crystal structure, and near-IR absorption.
Synthesis of fused bis-anthracene porphyrin monomers and dimers has been achieved by oxidative ring closure using FeCl(3) and Sc(OTf)(3)/DDQ, respectively. The fused compounds display red-shifted absorption spectra with maxima in the near-IR at 973 and 1495 nm, respectively, and small electrochemica...
| Main Authors: | , , |
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| Format: | Journal article |
| Jezik: | English |
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2010
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| _version_ | 1826299304337211392 |
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| author | Davis, N Thompson, A Anderson, H |
| author_facet | Davis, N Thompson, A Anderson, H |
| author_sort | Davis, N |
| collection | OXFORD |
| description | Synthesis of fused bis-anthracene porphyrin monomers and dimers has been achieved by oxidative ring closure using FeCl(3) and Sc(OTf)(3)/DDQ, respectively. The fused compounds display red-shifted absorption spectra with maxima in the near-IR at 973 and 1495 nm, respectively, and small electrochemical HOMO-LUMO gaps. The crystal structure of the fully fused bis-anthracene porphyrin shows that it has a regular planar pi-system. |
| first_indexed | 2024-03-07T04:59:53Z |
| format | Journal article |
| id | oxford-uuid:d7eafb8c-d6c4-4ef4-ae0a-2c4bf209c33b |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T04:59:53Z |
| publishDate | 2010 |
| record_format | dspace |
| spelling | oxford-uuid:d7eafb8c-d6c4-4ef4-ae0a-2c4bf209c33b2022-03-27T08:44:27ZBis-anthracene fused porphyrins: synthesis, crystal structure, and near-IR absorption.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:d7eafb8c-d6c4-4ef4-ae0a-2c4bf209c33bEnglishSymplectic Elements at Oxford2010Davis, NThompson, AAnderson, HSynthesis of fused bis-anthracene porphyrin monomers and dimers has been achieved by oxidative ring closure using FeCl(3) and Sc(OTf)(3)/DDQ, respectively. The fused compounds display red-shifted absorption spectra with maxima in the near-IR at 973 and 1495 nm, respectively, and small electrochemical HOMO-LUMO gaps. The crystal structure of the fully fused bis-anthracene porphyrin shows that it has a regular planar pi-system. |
| spellingShingle | Davis, N Thompson, A Anderson, H Bis-anthracene fused porphyrins: synthesis, crystal structure, and near-IR absorption. |
| title | Bis-anthracene fused porphyrins: synthesis, crystal structure, and near-IR absorption. |
| title_full | Bis-anthracene fused porphyrins: synthesis, crystal structure, and near-IR absorption. |
| title_fullStr | Bis-anthracene fused porphyrins: synthesis, crystal structure, and near-IR absorption. |
| title_full_unstemmed | Bis-anthracene fused porphyrins: synthesis, crystal structure, and near-IR absorption. |
| title_short | Bis-anthracene fused porphyrins: synthesis, crystal structure, and near-IR absorption. |
| title_sort | bis anthracene fused porphyrins synthesis crystal structure and near ir absorption |
| work_keys_str_mv | AT davisn bisanthracenefusedporphyrinssynthesiscrystalstructureandnearirabsorption AT thompsona bisanthracenefusedporphyrinssynthesiscrystalstructureandnearirabsorption AT andersonh bisanthracenefusedporphyrinssynthesiscrystalstructureandnearirabsorption |