Reactions of titanium imido complexes with alpha-diimines: complexation versus Ti=N/C=N bond metathesis
The reactions of the titanium imido complexes [Ti(NR)Cl2(py)3] (R = But 1, C6H3Me2-2,6 2 or C6H3Pri 2-2,6 3) with α-diimines (1,4-diaza-1,3-butadienes) of the type ArNC(R′)C(R′)NAr (Ar = phenyl or substituted phenyl, R′ = H or methyl) are reported. The reaction products and metal complex stability a...
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Format: | Journal article |
Published: |
1998
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