Reactions of titanium imides and hydrazides with boranes

We report the first reactions of titanium imido, alkylidene hydrazido and dimethylhydrazido compounds with the boranes H2BTex, 9-BBN, HBArF 2 and HBPin (Tex = tert-hexyl; ArF = C6F5). Reactions of Cp*Ti{MeC(Ni Pr)2}(NTol) with H2BTex, 9-BBN or HBArF 2 resulted in the hydridebridged adducts Cp*Ti{Me...

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Bibliographic Details
Main Authors: Mellino, S, Stevenson, L, Clot, E, Mountford, P
Format: Journal article
Published: American Chemical Society 2017