Halide anions driven self-assembly of haloperfluoroarenes: Formation of one-dimensional non-covalent copolymers

The supramolecular organization in six solid assemblies involving iodo- and bromoperfluoroarene derivatives is described. Single crystal X-ray analyses show that the formation of the supramolecular architectures is controlled by I-⋯Br-ArF, I-⋯I-ArF, Br-⋯I-ArF, and Cl-⋯I-ArF halogen bondings thus pro...

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Bibliographic Details
Main Authors: Abate, A, Biella, S, Cavallo, G, Meyer, F, Neukirch, H, Metrangolo, P, Pilati, T, Resnati, G, Terraneo, G
Format: Journal article
Published: 2009