Efficient acyclic stereocontrol using the tethered aminohydroxylation reaction.
[reaction: see text] The tethered aminohydroxylation (TA) of acyclic allylic carbamates has been achieved in a stereospecific and stereoselective manner. Unusually high levels of stereocontrol were observed in the oxidation of 1,1-disubstituted substrates.
Váldodahkkit: | , , , |
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Materiálatiipa: | Journal article |
Giella: | English |
Almmustuhtton: |
2004
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