The solution conformation and rotational dynamics of tetramesityldiphosphane studied by 2-D NMR spectroscopy

Detailed proton and 13C dynamic NMR and 2-D EXSY studies of tetramesityldiphosphane at a field of 11.8 T over the temperature range 193-313 K showed that rotations about the P-P bond and two types of P-Cipso bond are associated with three different barriers. This supports a gauche conformation of th...

Full description

Bibliographic Details
Main Authors: McFarlane, W, Rees, N, Constanza, L, Patel, M, Colquhoun, I
Format: Journal article
Language:English
Published: 2000