Electronic delocalization in the radical cations of porphyrin oligomer molecular wires
The radical cations of a family of π-conjugated porphyrin arrays have been investigated: linear chains of N = 1-6 porphyrins, a 6-porphyrin nanoring and a 12-porphyrin nanotube. The radical cations were generated in solution by chemical and electrochemical oxidation, and probed by vis-NIR-IR and EPR...
| Main Authors: | , , , , , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
American Chemical Society
2017
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