Double CO2 activation by 14-electron η(8)-permethylpentalene titanium dialkyl complexes.
The novel 14 electron species η(8)-Pn*TiR2 (Pn* = C8Me6; R = Me, CH2Ph) have been synthesised and spectroscopically and structurally characterised. Subsequent reaction with CO2 leads to the activation and double insertion of CO2 into both Ti-alkyl bonds to form the electronically saturated η(8)-Pn*T...
| Main Authors: | , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
Royal Society of Chemistry
2015
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