Double CO2 activation by 14-electron η(8)-permethylpentalene titanium dialkyl complexes.

Double CO2 activation by 14-electron η(8)-permethylpentalene titanium dialkyl complexes.

The novel 14 electron species η(8)-Pn*TiR2 (Pn* = C8Me6; R = Me, CH2Ph) have been synthesised and spectroscopically and structurally characterised. Subsequent reaction with CO2 leads to the activation and double insertion of CO2 into both Ti-alkyl bonds to form the electronically saturated η(8)-Pn*T...

Bibliografski detalji
Glavni autori:	Cooper, RT, Chadwick, F, Ashley, A, O'Hare, D
Format:	Journal article
Jezik:	English
Izdano:	Royal Society of Chemistry 2015

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