(Dimethylamino)borylene and Related Complexes of Electron-Rich Metal Fragments: Generation of Nucleophile-Resistant Cations by Spontaneous Halide Ejection

Spontaneous halide ejection from a three-coordinate Lewis acid has been shown to offer a remarkable new route to cationic metal complexes featuring a linear, multiply bonded boron-donor ligand. The exploitation of electron-rich [CpM(PR 3) 2] fragments within boryl systems of the type L nMB(hal)NR 2...

Full description

Bibliographic Details
Main Authors: Addy, D, Phillips, N, Pierce, G, Vidovic, D, Kraemer, T, Mallick, D, Jemmis, E, Reid, G, Aldridge, S
Format: Journal article
Language:English
Published: 2012