Titanium and niobium imido complexes derived from diamidoamine ligands.
New groups 4 and 5 imido complexes derived from the diamidoamine ligand Me3SiN(CH2CH2NSiMe3)2 (N2N) are described. Reactions of Li2[N2N] with [Ti(NR)Cl2(py)3] gave compound 1 in which the N2N ligand adopts a fac-coordination mode. With [Nb(N1-Bu)Cl3(py)2], two different Nb(V) products were formed.
| Main Authors: | , , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2000
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