Synthesis and ethylene trimerisation capability of new chromium(II) and chromium(III) heteroscorpionate complexes.
Reaction of (Me(2)pz)(2)CHSiMe(2)N(H)R (R = (i)Pr or Ph) or (Me(2)pz)(2)CHSiMe(2)NMe(2) with CrCl(3)(THF)(3) or CrCl(2)(THF)(2) gave Cr{(Me(2)pz)(2)CHSiMe(2)NR(1)R(2)}Cl(3) (R(1) = H, R(2) = (i)Pr (10) or Ph (11); R(1) = R(2) = Me (15)) or Cr{(Me(2)pz)(2)CHSiMe(2)NR(1)R(2)}Cl(2)(THF) (R(1) = H, R(2)...
| Main Authors: | , , , , |
|---|---|
| Format: | Journal article |
| Language: | English |
| Published: |
2010
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