The room-temperature crystallisation of a one-dimensional gallium fluorophosphate, Ga(HPO4)(2)F center dot H3N(CH2)(3)NH3 center dot 2H(2)O, a precursor to three-dimensional microporous gallium fluorophosphates

The one-dimensional gallium fluorophosphate Ga(HPO4)2F·H3N(CH2)3NH3.2H2O 1 crystallises at room temperature from an aqueous mixture of Ga2O3, H3PO4, 1,3-diaminopropane, and HF; compound 1 converts to the three-dimensional microporous fluorophosphate ULM-3 on heating to 160 °C under hydrothermal cond...

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Bibliographic Details
Main Authors: Walton, R, Millange, F, Le Bail, A, Loiseau, T, Serre, C, O'Hare, D, Ferey, G
Format: Journal article
Language:English
Published: 2000