Origin of diastereocontrol in the oxy-Michael reactions of delta-lactol anions: a computational and experimental study.

Origin of diastereocontrol in the oxy-Michael reactions of delta-lactol anions: a computational and experimental study.

The diastereoselectivity in the alkylation and Michael addition of "naked" 6-substituted delta-lactolates has been studied by density functional (B3LYP) calculations with ab initio (MP2) energy refinements. The resulting proposed model for the origins of stereocontrol in this reaction has...

Бүрэн тодорхойлолт

Номзүйн дэлгэрэнгүй
Үндсэн зохиолчид:	Richardson, R, Hernandez-Juan, F, Ward, J, Dixon, D
Формат:	Journal article
Хэл сонгох:	English
Хэвлэсэн:	2008

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