Origin of diastereocontrol in the oxy-Michael reactions of delta-lactol anions: a computational and experimental study.

Origin of diastereocontrol in the oxy-Michael reactions of delta-lactol anions: a computational and experimental study.

The diastereoselectivity in the alkylation and Michael addition of "naked" 6-substituted delta-lactolates has been studied by density functional (B3LYP) calculations with ab initio (MP2) energy refinements. The resulting proposed model for the origins of stereocontrol in this reaction has...

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Những tác giả chính:	Richardson, R, Hernandez-Juan, F, Ward, J, Dixon, D
Định dạng:	Journal article
Ngôn ngữ:	English
Được phát hành:	2008

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